| Rank | AG | Name | Time |
|---|---|---|---|
| 🥇 | 🥇 | 🇵🇹Diana Simoes, 🇵🇹José Silva | 58:52 |
| 🥈 | 🥈 | 🇪🇸Miguel Prados, 🇪🇸Yadira Pérez Jiménez | +1:261:00:18 |
| 🥉 | 🥇 | 🇮🇪Megan Walsh, 🇮🇪James Maher | +0:071:00:25 |
| #4 | 🥉 | 🇪🇸Natalia Bermudez De Castro Angulo, 🇪🇸Emilio Aguayo Muñoz | +0:341:00:59 |
| #5 | 🥈 | 🇪🇸Manuela García, 🇪🇸Álvaro Caja Alcudia | +0:121:01:11 |
| #6 | #4 | 🇪🇸Isabel Macías Chow, 🇪🇸Luis Alberto Marco Contreras | +0:111:01:22 |
| #7 | #5 | 🇮🇸Simona Vareikaite, 🇮🇸Sigurjon Ernir Sturluson | +0:191:01:41 |
| #8 | 🥇 | 🇵🇹Tiago Lousa, 🇵🇹Marta Caetano | +0:071:01:48 |
| #9 | 🥉 | 🇬🇧Lewis O Malley, 🇬🇧Bekkie Vaudrey | +0:141:02:02 |
| #10 | #6 | 🇪🇸Mathilde Delorme, 🇺🇾Carlos Pombo | +0:171:02:19 |
| #11 | 🥈 | 🇪🇸Toni Chillaron Cano, 🇪🇸Cristina Manteiga | +0:041:02:23 |
| #12 | 🥉 | 🇪🇸Mikel Domenech Gonzalez, 🇪🇸Susana Merino | +0:171:02:40 |
| #13 | #7 | 🇪🇸Susana Alonso, 🇪🇸Jorge Gutiérrez | +0:061:02:46 |
| #14 | #8 | 🇪🇸Virginia Becerra Armas, 🇪🇸Cristo Javier Umpiérrez García | +0:041:02:50 |
| #15 | #4 | 🇪🇸Davide Oneda, 🇪🇸Alba Moreno Miralles | 1:02:50 |
| #16 | #9 | 🇮🇹Margherita Zamboni, 🇸🇪Stefan Kirjonen | +0:291:03:19 |
| #17 | #5 | 🇺🇾Sebastián Miguel Castagnaro Pereira, 🇺🇾Fiorella Maccio Mangarelli | +0:171:03:36 |
| #18 | #10 | 🇪🇸Pablo Hermo Villar, 🇪🇸Silvia García Lorenzo | 1:03:36 |
| #19 | #11 | 🇬🇧Ben Grierson, 🇬🇧Adele Battersby | +0:511:04:27 |
| #20 | #12 | 🇵🇹Paulo Caldas, 🇵🇹Inês Salgueiro | +0:041:04:31 |
| #21 | #4 | 🇪🇸Nilton Monteiro Leal, 🇪🇸Mónica Romero Rodríguez | +0:071:04:38 |
| #22 | #6 | 🇮🇪Michael Whelan, 🇮🇪Gráinne Kennedy | +0:101:04:48 |
| #23 | #13 | 🇵🇹Diogo Fonte, 🇵🇹Catarina Monteiro | +0:021:04:50 |
| #24 | #14 | 🇪🇸Esther Gil Robles, 🇪🇸Javier Gómez Cañego | +0:071:04:57 |
| #25 | #15 | 🇳🇴Heidi Lesteberg, 🇳🇴Ole Verås | +0:161:05:13 |
| #26 | #7 | 🇪🇸Javier Donés, 🇪🇸Claudia Rojo Cazorla | +0:111:05:24 |
| #27 | #5 | 🇪🇸Raul Refolio Márquez, 🇪🇸Marian Donoso Martín | +0:081:05:32 |
| #28 | #8 | 🇬🇧Joe Wilson, 🇬🇧Shona Mcbean Kyle | +0:031:05:35 |
| #29 | #6 | 🇪🇸Daniel Arazola López, 🇪🇸Pilar Santafé Martínez | +0:071:05:42 |
| #30 | #16 | 🇪🇸Luis Pelluz, 🇪🇸Marta Olaz | +0:021:05:44 |
| #31 | #7 | 🇬🇧Sean Adrian Sanderson, 🇪🇸Melina De León Rodríguez | +0:151:05:59 |
| #32 | #9 | 🇮🇪Ellie Pyke, 🇮🇪Scott Ogrady | +0:111:06:10 |
| #33 | #17 | 🇮🇪Rachel Farrell, 🇮🇪Johnny Madden | +0:011:06:11 |
| #34 | #18 | 🇪🇸Tamara Lechuga Tellez, 🇪🇸Juan Manuel Perez Rubio | +0:091:06:20 |
| #35 | #10 | 🇪🇸Jaime Camazón, 🇪🇸Patricia Curbelo Armas | +0:121:06:32 |
| #36 | #19 | 🇪🇸Mathias Santiago Cejas, 🇪🇸Clara Guiscafre Ferrer | +0:031:06:35 |
| #37 | #11 | 🇪🇸Ferran Rodríguez, 🇪🇸Serena Juan Lobato | +0:101:06:45 |
| #38 | #20 | 🇪🇸Rocío Benítez García, 🇪🇸Sergio Malagón Casilda | +0:101:06:55 |
| #39 | #21 | 🇨🇭Danny Loureiro, 🇨🇭Hélène Pierdona | +0:021:06:57 |
| #40 | #12 | 🇬🇧Harrison Stevens, 🇬🇧Sophie Harper | +0:211:07:18 |
| #41 | #13 | 🇬🇧Japke Delicado, 🇬🇧Julian Delicado | +0:031:07:21 |
| #42 | #8 | 🇪🇸Yeray Cabrera Padrón, 🇪🇸Sara Muñoz Guerrero | +0:091:07:30 |
| #43 | #14 | 🇩🇰Simone Rosenbøl, 🇩🇰Steffen Andersen | +0:051:07:35 |
| #44 | #9 | 🇪🇸Qing Inmaculada Zhou Chen, 🇪🇸Alejandro López Ruíz | +0:021:07:37 |
| #45 | #15 | 🇮🇪Soha Smyth, 🇮🇪Jack Murray | +0:101:07:47 |
| #46 | #10 | 🇬🇧Orsten Gardner, 🇬🇧Carly Waine | +0:081:07:55 |
| #47 | #16 | 🇪🇸David Pérez Ramos, 🇪🇸Olivia Roura Garcia | +0:091:08:04 |
| #48 | #17 | 🇮🇪Cathal Mcmullan, 🇮🇪Grace Fitzgerald | +0:031:08:07 |
| #49 | #18 | 🇪🇸Daniel Ruiz Marin, 🇪🇸Sofia Fierros Daza | +0:021:08:09 |
| #50 | #22 | 🇧🇪Joachim Callebaut, 🇧🇪Eva Tritsmans | +0:011:08:10 |