| Rank | AG | Name | Time |
|---|---|---|---|
| 🥇 | — | 🇪🇸Daniel Redondo Muñoz, Ainegue Del Olmo Jimenez | 57:24 |
| 🥇 | 🥇 | 🇪🇸Isabel Macías Chow, 🇪🇸Luis Alberto Marco Contreras | +0:3057:54 |
| 🥉 | 🥇 | 🇪🇸Irene Teixeira, 🇪🇸David Teixeira | +0:4458:38 |
| 🥈 | — | 🇪🇸David Teixeira, Irene Teixeira | 58:38 |
| 🥉 | — | 🇪🇸Isma Mateo Serrano, 🇪🇸Eider Alonso | +0:0158:39 |
| 🥈 | 🥈 | 🇪🇸Noelia González, 🇪🇸David González | +0:2559:04 |
| 🥉 | 🥇 | 🇪🇸Jennifer Marin Palacios, 🇪🇸Alvaro Garcia Mozun | +0:0759:11 |
| #4 | 🥇 | 🇫🇷Guillaume Criado, Emilie Morier | +0:0159:12 |
| #4 | — | 🇫🇷Alexandre Hanne, 🇫🇷Fanny Bielakoff | +0:2259:34 |
| #5 | — | 🇬🇧Joseph Davies, 🇬🇧Rebecca Thomas | +0:2259:56 |
| #6 | — | 🇬🇧Cerys Messenger, 🇬🇧Robert Cowan | +0:281:00:24 |
| #5 | 🥉 | 🇦🇺Luke Bradshaw, 🇳🇱Petra Blackburn | +0:491:01:13 |
| #12 | #5 | 🇵🇹Catarina Maria, 🇵🇹José Pedro | +0:311:01:44 |
| #7 | — | 🇵🇹José Pedro, Catarina Maria | 1:01:44 |
| #13 | #6 | 🇪🇸Jesús De Lope, 🇪🇸Inés María Vázquez | +0:031:01:47 |
| #8 | — | 🇪🇸Jesús De Lope, Inés María Vázquez | 1:01:47 |
| #6 | 🥈 | 🇬🇧Simon Flowers, 🇬🇧Sam Francis | +0:011:01:48 |
| #15 | #5 | 🇵🇹Diogo Pereira, 🇵🇹Vanessa Sousa | +0:171:02:05 |
| #7 | 🥈 | 🇵🇹Diogo Pereira, Vanessa Sousa | 1:02:05 |
| #16 | #6 | 🇪🇸Claudia Maestre Roldán, 🇪🇸Guillermo Pallarés | +0:091:02:14 |
| #8 | 🥉 | 🇪🇸Guillermo Pallarés, Claudia Maestre Roldán | 1:02:14 |
| #9 | — | 🇨🇱Pablo Mardones, 🇱🇻Paula Grebe | +0:041:02:18 |
| #18 | #7 | 🇪🇸Roger Vidal, 🇪🇸Laura Monterde | +0:011:02:19 |
| #10 | — | 🇪🇸Roger Vidal, Laura Monterde | 1:02:19 |
| #9 | #4 | 🇪🇸Eduardo Flecha Perez, 🇪🇸Diana Martin Hidalgo | +0:141:02:33 |
| #11 | — | 🇫🇷Benjamin Cloarec, 🇫🇷Camille Cayot | +0:311:03:04 |
| #10 | #5 | 🇪🇸Ainize Lizarralde, 🇪🇸Xabi Muñoz | +0:051:03:09 |
| #12 | — | 🇪🇸Francisco Hijazo Zabala, 🇪🇸Elena Sanchez Sanchez | +0:011:03:10 |
| #11 | 🥇 | 🇬🇧Gary Rothwell, 🇬🇧Debby Minkoff | +0:041:03:14 |
| #12 | #4 | 🇬🇧Saskia Devereux, 🇬🇧Sebastan James Devereux | +0:121:03:26 |
| #13 | — | 🇬🇧Alexander Neville, Stephanie Dollimore | 1:03:26 |
| #14 | — | 🇨🇭Samira Cathomas, 🇨🇭Thomas Stalder | +0:031:03:29 |
| #27 | #12 | 🇪🇸Jose Manuel Susavila Turnes, 🇪🇸Adriana Gondelle Pájaro | +0:181:03:47 |
| #13 | #6 | 🇪🇸Jose Manuel Susavila Turnes, Adriana Gondelle Pájaro | 1:03:47 |
| #14 | 🥉 | 🇪🇸Urko Villasante Moreno, 🇪🇸Virginia Araujo Esteban | +0:041:03:51 |
| #29 | #13 | 🇪🇸Ana Junquera Méndez, 🇪🇸Sergio González Longo | +0:071:03:58 |
| #15 | #7 | 🇪🇸Ana Junquera Méndez, Sergio González Longo | 1:03:58 |
| #15 | — | 🇫🇷Solenn Glemas, Liam Carrea | +0:021:04:00 |
| #31 | #14 | 🇪🇸Liz Mariela Soto Núñez, 🇪🇸Jakoba Sánchez Behobide | +0:121:04:12 |
| #16 | #8 | 🇪🇸Liz Mariela Soto Núñez, Jakoba Sánchez Behobide | 1:04:12 |
| #32 | #15 | 🇪🇸Gonzalo Mejuto, 🇪🇸Ariadna Casal | +0:021:04:14 |
| #16 | — | 🇪🇸Gonzalo Mejuto, Ariadna Casal | 1:04:14 |
| #17 | — | 🇬🇧Kyle Henderson, 🇬🇧Johanna Basford | +0:031:04:17 |
| #34 | #16 | 🇪🇸Cristina Lopez, 🇪🇸Diego Delgado | +0:031:04:20 |
| #18 | — | 🇪🇸Diego Delgado, Cristina Lopez | 1:04:20 |
| #19 | — | 🇵🇹Diogo Braz Freitas, Inga Braz Freitas | +0:071:04:27 |
| #17 | #4 | 🇪🇸Mercedes Ferrando Riera, Toni Camarasa Tous | +0:011:04:28 |
| #37 | #12 | 🇪🇸Asier Iregui, 🇪🇸Paula Migueles | +0:051:04:33 |
| #20 | — | 🇪🇸Paula Migueles, Asier Iregui | 1:04:33 |
| #38 | #13 | 🇪🇸Cristian Puerto, 🇪🇸Andrea Ainciburu Barrios | +0:091:04:42 |